Open AccessModified Becke-Johnson exchange potential: improved modeling of lead halides for solar cell applications
Author(s) -
Radi A. Jishi
Publication year - 2016
Publication title -
aims materials science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.367
H-Index - 16
eISSN - 2372-0484
pISSN - 2372-0468
DOI - 10.3934/matersci.2016.1.149
Subject(s) - halide , chemistry , density functional theory , absorption (acoustics) , ionic bonding , coupling (piping) , analytical chemistry (journal) , inorganic chemistry , atomic physics , computational chemistry , ion , physics , materials science , optics , organic chemistry , chromatography , metallurgy
We report first-principles calculations, within density functional theory, on the lead halide compounds PbCl2, PbBr2, and CH3NH3PbBr3−xClx, taking into account spin-orbit coupling. We show that, when the modified Becke-Johnson exchange potential is used with a suitable choice of defining parameters, excellent agreement between calculations and experiment is obtained. The computational model is then used to study the effect of replacing the methylammonium cation in CH3NH3PbI3 and CH3NH3PbBr3 with either N2H5+or N2H3+, which have slightly smaller ionic radii than methylammonium. We predict that a considerable downshift in the values of the band gaps occurs with this replacement. The resulting compounds would extend optical absorption down to the near-infrared region, creating excellent light harvesters for solar cells