Open AccessTransition to process model parameters radical polymerization
Author(s) -
M. N. Patrusheva,
Eleanor R. Mukhamedzyanova,
Р. М. Хузаханов
Publication year - 2020
Publication title -
butlerovskie soobŝeniâ
Language(s) - English
Resource type - Journals
ISSN - 2074-0212
DOI - 10.37952/roi-jbc-01/20-61-3-17
Subject(s) - polymerization , radical polymerization , process (computing) , polymer chemistry , monomer , thermodynamics , materials science , chemistry , computer science , polymer , organic chemistry , physics , operating system
A mathematical transition to model parameters is presented, which are decisive in the preparation of a mathematical model of the radical polymerization process taking into account the gel effect. Using the mathematical model of radical thermal polymerization of styrene as an example, the derivation of parameters is considered, taking into account which the values of the number-average and mass-average molecular weights obtained as a result of calculation using similar parameters given in the previously published literature are confirmed. The difference of the study is the description of a step-by-step transition to the model parameters, applicable to the description of the radical polymerization process of other monomers, taking into account the gel effect.