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Complex formation of REEs with polydentate organic ligands
Author(s) -
М. В. Белобелецкая,
Н. И. Стеблевская,
М. А. Медков
Publication year - 2020
Publication title -
vestnik dalʹnevostočnogo otdeleniâ rossijskoj akademii nauk
Language(s) - English
Resource type - Journals
ISSN - 0869-7698
DOI - 10.37102/08697698.2020.214.6.001
Subject(s) - europium , denticity , terbium , chemistry , extraction (chemistry) , ligand (biochemistry) , infrared spectroscopy , complex formation , luminescence , phase (matter) , inorganic chemistry , organic chemistry , polymer chemistry , crystal structure , materials science , receptor , biochemistry , ion , optoelectronics
Исследовано комплексообразование европия и тербия с полифункциональными органическими соединениями – β-дикетонами, органическими кислотами. Состав комплексов изучен экстракционным методом, ИК и люминесцентной спектроскопией.Установлено, что при экстракции РЗЭ смешанными экстрагентами идет эффективное комплексообразование РЗЭ в органической фазе. Показана возможность синтеза из насыщенных экстрактов разнолигандных координационных соединений РЗЭ, выделены индивидуальные кристаллические комплексы. The complex formation of europium and terbium with polyfunctional organic compounds: β-diketones, organic acids were investigated. The composition of the complexes was studied by extractive method, infrared and luminescent spectroscopy.It was established that during the extraction of REE by mixed extractants there is an effective complex formation of REE in the organic phase. The possibility of synthesis of different ligand coordination compounds of REE from saturated extracts was shown and individual crystalline complexes were isolated.

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