Open AccessAZIDATION OF CHLOREX WITH SODIUM AZIDE IN WATER, DIOXANE AND APROTIC DIPOLAR SOLVENTS IN THE PRESENCE OF BENZYL BUTYL DIMETHYL AMMONIUM BROMIDE
Author(s) -
Artyom I. Babaev
Publication year - 2021
Publication title -
izvestiâ sankt-peterburgskogo gosudarstvennogo tehnologičeskogo instituta (tehničeskogo universiteta)
Language(s) - English
Resource type - Journals
ISSN - 1998-9849
DOI - 10.36807/1998-9849-2021-58-84-56-61
Subject(s) - sodium azide , solvent , ammonium bromide , chemistry , bromide , hydrogen bromide , ammonium , benzyl alcohol , organic chemistry , catalysis , pulmonary surfactant , bromine , biochemistry
In this work, the azidation of 2,2'-dichloroethyl ether (chlorex) in aprotic bipolar solvents, dioxane and water at various solvent / chlorex ratios was studied. The choice of the catalyst for the azidation reaction was substantiated and its effect on the degree of chlorex conversion was shown. Optimal conditions for azidation were selected.