Open AccessThermodynamics and cooperativeness of the spin crossover
Author(s) -
Roman Boča
Publication year - 2020
Publication title -
nova biotechnologica et chimica
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.212
H-Index - 9
eISSN - 1339-004X
pISSN - 1338-6905
DOI - 10.36547/nbc.v19i2.769
Subject(s) - cooperativeness , chemistry , spin crossover , condensed matter physics , spin (aerodynamics) , thermodynamics , state (computer science) , magnetic susceptibility , statistical physics , physics , psychology , crystallography , mathematics , social psychology , personality , algorithm , temperament
Spin transition – a passage from the low-spin electronic state to the high-spin one of Fe(III) and Fe(II) complexes is assessed from several points of view: theoretical modelling, magnetic susceptibility data, and calorimetric measurements. The concept of the cooperativeness in the solid state is discussed in detail. Thermodynamic parameters are mutually correlated for a set of analogous Fe(III) complexes by using modern statistical methods.