Open AccessExcess Thermodynamic Properties and Molecular Interactions in Binary Liquid Mixture of o-xylene and N-nonane
Author(s) -
Baljinder K. Gill,
Minakshi,
V. K. Ratttan
Publication year - 2020
Publication title -
international journal of innovative technology and exploring engineering
Language(s) - English
Resource type - Journals
ISSN - 2278-3075
DOI - 10.35940/ijitee.f3766.049620
Subject(s) - thermodynamics , nonane , viscometer , viscosity , refractive index , intermolecular force , xylene , binary number , refractometer , chemistry , atmospheric pressure , materials science , organic chemistry , molecule , physics , toluene , arithmetic , optoelectronics , mathematics , meteorology
Experimentally measured data for viscosity and refractive index of (o-Xylene + n-Nonane) binary mixture are reported in this research paper for various compositions for three different temperatures at atmospheric pressure. Modified Ubbelholde viscometer and Abbe-3L Refractometer were used for experimental measurements. Deviation in molar refraction (ΔR) and deviation in viscosity (Δη) w.r.t composition have been calculated from the experimental data. ‘Grunberg and Nissan’ equation and Herric’s Correlation were used to correlate the viscosity data. Excess thermodynamic properties were fitted to Redlich-Kister equation. Coefficients and standard deviations, hence obtained are reported. Variation in Excess Thermodynamic properties for the mixture have been discussed in terms of intermolecular interactions.