Open AccessSTUDY OF THE INFLUENCE OF DISPERSITY AND CHEMICAL COMPOSITION OF NICKEL RENEUAL ALLOYS ON THE SPECIFICITY OF REDUCTION OF ADAMANTANE-CONTAINING UNSATURED NITRILE
Author(s) -
И. А. Новаков,
Б. С. Орлинсон,
E. N. Saveliev,
E. A. Alykova,
A. M. Pichugin,
M. A. Nakhod,
M. N. Kovaleva,
Д. Н. Небыков,
P. E. Antonova,
L. A. Solovyova,
A. Yu. Krupnova,
A. D. Dubinina
Publication year - 2021
Publication title -
izvestiâ volgogradskogo gosudarstvennogo tehničeskogo universiteta
Language(s) - English
Resource type - Journals
ISSN - 1990-5297
DOI - 10.35211/1990-5297-2021-12-259-64-70
Subject(s) - nitrile , nickel , adamantane , chemistry , double bond , alloy , dispersity , reduction (mathematics) , composition (language) , organic chemistry , mathematics , linguistics , philosophy , geometry
The regularities of the reduction of adamantane-containing unsaturated nitrile-nickel-aluminum alloy are investigated. It has been shown that under the conditions of synthesis it is possible to carry out the simultaneous reduction of both the double bond and the nitrile group. It was found that the reduction of nitriles containing 1 hydroxyl group in the position leads to a significant decrease in the rate of the process. The effect of the grain size composition of the alloy and damping additives on the reduction of unsaturated nitriles has been studied.