Open AccessTHE PROSPECT OF USING THE BICOMPONENT COAGULANT OF MOLLASES "SODIUM CHLORIDE" WNEN PRODUCTION OF OIL-FILLED RUBBERS
Author(s) -
Н. С. Никулина,
T M Bulatetskaya,
N. Patrusheva,
Л. А. Власова,
Natalia Sannikova,
С. С. Никулин
Publication year - 2020
Publication title -
vestnik bgtu im. v.g. šuhova
Language(s) - English
Resource type - Journals
ISSN - 2071-7318
DOI - 10.34031/2071-7318-2020-5-9-81-88
Subject(s) - synthetic rubber , natural rubber , defoamer , chemistry , pulp and paper industry , sodium , chemical engineering , emulsion , organic chemistry , materials science , dispersant , physics , optics , engineering , dispersion (optics)
Currently, special attention is paid to improving the production technology of synthetic rubbers. Synthetic rubbers are in great demand in the tire and rubber industry, in the manufacture of composite materials for various purposes, etc. Every year, the requirements for both the quality of manufactured products and the environmental friendliness of their production are increasing. One of the problematic stages in the production of rubbers by emulsion polymerization is the stage of their separation from latex. The paper considers the possibility of using a bis-compound coagulant consisting of a by-product of beet sugar production of molasses and traditional sodium chloride in the process of obtaining oil-filled rubbers. It was found that the use of this bis-compound coagulant to reduce the agricul-ture stability of synthetic latexes reduces the consumption of coagulating agents by 3-4 times. It is shown that the main coagulating component of molasses is betaines, which are present in its composition. Sodium chloride contributes to the coagulation process by the concentration mechanism, and betaine – by the neutralization mechanism, based on the chemical interaction of surfactant anions with the positively charged ammonium group of the betaine molecule. The use of a bis-compound coagulant reduces environmental pollution by components of the emulsion system. The water phase remaining after the rubber is extracted from latex can be used to prepare a solution of molasses and sulfuric acid. Rubber mixtures prepared on the basis of experimental samples of rubber meet the requirements in terms of their parameters.