
Factores limitantes en la producción del biodiésel de Jatropha curcas L
Author(s) -
Ana Avellán,
Segundo García,
Gabriel Burgos,
Carlos Roberto Moreira,
Oswaldo García,
Carlos Banchón
Publication year - 2020
Publication title -
revista de investigaciones en energía, medio ambiente y tecnología
Language(s) - English
Resource type - Journals
ISSN - 2588-0721
DOI - 10.33936/riemat.v4i2.2188
Subject(s) - jatropha curcas , transesterification , biodiesel , chemistry , methanol , sodium hydroxide , calcium hydroxide , biodiesel production , catalysis , calcium oxide , biofuel , nuclear chemistry , organic chemistry , botany , microbiology and biotechnology , biology
In order to reduce production costs of biodiesel, minimum transesterification conditions were herein evaluated. Limiting factors were determined to use calcium oxide and hydroxide catalysts, at different doses and concentrations in the transesterification of Jatropha curcas L. oil and methanol. It was determined that the presence of water, and content of free fatty acids (0,423-2,53% acidity) in the Jatropha oil are just a minimum inhibition factors, in comparison with atmospheric reaction conditions. In contrast, the 10:1 molar ratio of methanol and oil allowed a 98,9% yield of biodiesel when sodium hydroxide was used as catalyst. The same yield was obtained with or without oil esterification. In perspective, avoiding the poisoning of heterogeneous catalysts is still under study in the search for catalysts recovery from the reaction medium.
Index Terms—transesterification, nucleophilic reaction, oil, energy, biofuel.