Highly Tunable Emission by Halide Engineering in Lead-Free Perovskite-Derivative Nanocrystals: The Cs2SnX6 (X = Cl, Br, Br/I, I) System | Zendy

Alessandro Veronese | Zendy; M. Patrini | Zendy; Daniele Bajoni | Zendy; Carlo Ciarrocchi | Zendy; Paolo Quadrelli | Zendy; Lorenzo Malavasi | Zendy

Open Access

Highly Tunable Emission by Halide Engineering in Lead-Free Perovskite-Derivative Nanocrystals: The Cs2SnX6 (X = Cl, Br, Br/I, I) System

Author(s) -

Alessandro Veronese,

M. Patrini,

Daniele Bajoni,

Carlo Ciarrocchi,

Paolo Quadrelli,

Lorenzo Malavasi

Publication year - 2020

Publication title -

frontiers in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.027

H-Index - 52

ISSN - 2296-2646

DOI - 10.3389/fchem.2020.00035

Subject(s) - halide , perovskite (structure) , nanocrystal , derivative (finance) , lead (geology) , materials science , crystal engineering , chemistry , inorganic chemistry , chemical engineering , photochemistry , nanotechnology , crystallography , crystal structure , engineering , supramolecular chemistry , geomorphology , geology , financial economics , economics

Nanocrystals of Cs 2 SnX 6 (X = Cl, Br, Br 0.5 I 0.5 , and I) have been prepared by a simple, optimized, hot-injection method, reporting for the first time the synthesis of Cs 2 SnCl 6 , Cs 2 SnBr 6 , and mixed Cs 2 Sn(I 0.5 Br 0.5 ) 6 nanocrystalline samples. They all show a cubic crystal structure with a linear scaling of lattice parameter by changing the halide size. The prepared nanocrystals have spherical shape with average size from 3 to 6 nm depending on the nature of the halide and span an emission range from 444 nm (Cs 2 SnCl 6 ) to 790 nm (Cs 2 SnI 6 ) with a further modulation provided by mixed Br/I systems.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research