Open AccessSTUDY OF SEDIMENTS OF COLLECTING AGENTS IN ELEMENTARY FLOTATION ACT
Author(s) -
T. G. Gavrilova,
D. M. Tsitsilina
Publication year - 2021
Publication title -
interèkspo geo-sibirʹ
Language(s) - English
Resource type - Journals
ISSN - 2618-981X
DOI - 10.33764/2618-981x-2021-2-3-162-170
Subject(s) - desorption , sorption , bubble , metal , chemical engineering , mineral , chemistry , liquid metal , mineral processing , mechanism (biology) , kinetic energy , materials science , adsorption , organic chemistry , mechanics , physics , engineering , quantum mechanics
The operating mechanism of physically sorbed derivatives of collector obtained at a nonstoichiometric ratio between collecting agents with heavy metal salts is proposed. It is found that by changing the ratio of the components, it is possible to adjust their surface-active properties with respect to the gas-liquid interface and, consequently, the ability to remove the kinetic restriction to the formation of flotation contact. The physical form of sorption on a mineral can be represented by collector sediments and ion-molecular associates. The research results show that when the interlayer breaks through, these forms can desorb from the mineral and spread over the bubble surface, dragging the liquid from the interlayer into motion, thereby “drying” the mineral surface. In turn, the removal of liquid from the interlayer leads to a reduction in the induction time, which affects the efficiency of flotation. The results make it possible to reveal the mechanism of flotation activation with heavy metal salts and can be used in the development of fundamentally new engineering solutions.