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GENERALIZED MODEL OF CHEMICAL KINETIC OF DETONATION COMBUSTION OF GASEOUS HYDROCARBONS
Author(s) -
P. A. Fomin
Publication year - 2019
Publication title -
interèkspo geo-sibirʹ
Language(s) - English
Resource type - Journals
ISSN - 2618-981X
DOI - 10.33764/2618-981x-2019-9-72-76
Subject(s) - detonation , combustion , ordinary differential equation , thermodynamics , simplicity , kinetic energy , mechanics , chemical reaction , chemistry , differential equation , materials science , physics , classical mechanics , mathematics , mathematical analysis , explosive material , biochemistry , organic chemistry , quantum mechanics
A two-step generalized model of chemical kinetics of detonation combustion of propylene is presented. The model is consistent with the second law of thermodynamics and Le Chatelier’s principle. Constants of the models have a clear physical meaning. Owing to the simplicity (it includes only one ordinary differential equation) and high accuracy, the model can be used in multi-dimensional numerical calculations of detonation wave parameters and multi-front cellular structure.

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