Open AccessThe Optical Properties of Dy3+ Doped LaPO4 Phosphors Prepared by Solid State Reaction Method
Author(s) -
Ch. Atchyutha Rao,
Karanukar Shakampally,
K. V. R. Murthy
Publication year - 2021
Publication title -
journal of scientific research
Language(s) - English
Resource type - Journals
eISSN - 2070-0245
pISSN - 2070-0237
DOI - 10.3329/jsr.v13i3.53287
Subject(s) - phosphor , photoluminescence , analytical chemistry (journal) , materials science , dysprosium , luminescence , scanning electron microscope , fourier transform infrared spectroscopy , doping , emission spectrum , solid state lighting , spectroscopy , ion , optoelectronics , light emitting diode , optics , spectral line , chemistry , inorganic chemistry , physics , organic chemistry , chromatography , quantum mechanics , astronomy , composite material
Luminescent nanomaterials are used in everyday life due to their employment in distinct fields of science and technology, like cathode ray tubes (CRTs), flat panel display devices, temperature sensors, lasers, solar-cells, biological imaging, and solid-state lighting but also as carriers for miscellaneous therapeutic drugs. We have prepared dysprosium Dy3+ (0.5 mol %) doped lanthanum phosphate (LaPO4) phosphor by solid state reaction method. The excitation spectra of synthesized phosphor at 595 nm monitoring were composed of broadband and a series of sharp peaks, the strongest excitation peak at 254, 271, and 350 nm. The main emission spectra of samples under 254, 271, and 350 nm excitation are Dy3+ (0.5 mol %) doped LaPO4 phosphor observed at 477 and 573 nm corresponding to blue and yellow color. The broadband emission is the characteristic of the allowed f-h transition of Dy3+ ions. The corresponding emission band is observed due to the (blue emission) 4f9/2→6h15/2, (yellow emission) 4f9/2→6h13/2 transition of Dy3+ ions. All the samples have been characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and photoluminescence (PL) techniques.