Open AccessX-ray structure of hexamethyl benzenehexacarboxylate, [C<sub>6</sub>(COOCH<sub>3</sub>)<sub>6</sub>]
Author(s) -
Shishir Ghosh,
Kamal Hossain,
Shariff E. Kabir,
Nasreen Begum
Publication year - 1970
Publication title -
journal of bangladesh academy of sciences
Language(s) - English
Resource type - Journals
eISSN - 2224-7270
pISSN - 0378-8121
DOI - 10.3329/jbas.v34i2.6866
Subject(s) - dimethyl acetylenedicarboxylate , monoclinic crystal system , yield (engineering) , chemistry , crystallography , crystal structure , stereochemistry , physics , catalysis , organic chemistry , cycloaddition , thermodynamics
The thermal treatment of [Ru2(CO)6(μ-η1,η2-C4H3O){μ-P(C4H3O)2}] 1 with dimethyl acetylenedicarboxylate (DMAD) at 110 °C leads to cyclotrimerization of DMAD. The cyclotrimerization product hexamethyl benzenehexacarboxylate, [C6(COOCH3)6] 2, was obtained in 37% yield and characterized by a combination of spectroscopic data and single crystal X-ray diffraction study. Compound 2 crystallizes in the monoclinic space group P1bar with a = 10.3002(12), b = 11.0371(13), c = 18.781(2) Å, α = 76.148(2), β = 87.390(2), γ = 74.001(2)°, Z = 4 and V = 1992.2(4) Å3. Key words: Cyclotrimerization; Dimethyl acetylenedicarboxylate; X-ray structure DOI: 10.3329/jbas.v34i2.6866Journal of Bangladesh Academy of Sciences, Vol. 34, No. 2, 197-200, 2010