Open AccessSurface Functionalized Halloysite with N-[3-(Trimethoxysilyl)Propyl] Ethylenediamine for Chromium and Nickel Adsorption from Aqueous Solution
Author(s) -
Sulyani Fitri,
Amri Yahya,
Ahmad Y. Sheikh,
Mohd Samsuri Ghazali,
Is Fatimah
Publication year - 2021
Publication title -
biointerface research in applied chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.216
H-Index - 11
ISSN - 2069-5837
DOI - 10.33263/briac126.72057213
Subject(s) - adsorption , aqueous solution , halloysite , ethylenediamine , chemisorption , chromium , chemistry , enthalpy , crystallinity , sorption , fourier transform infrared spectroscopy , inorganic chemistry , nuclear chemistry , materials science , chemical engineering , organic chemistry , thermodynamics , physics , engineering , composite material , crystallography
In this study, -[3-(trimethoxysilyl)propyl] ethylenediamine - modified Indonesian natural halloysite was applied for Cr(III) and Ni(II) adsorption from aqueous solution. The studies include the physicochemical characterization of the synthesized material by using XRD, SEM, gas sorption analyzer, and FTIR analyses. Furthermore, the adsorption experiments were performed at a batch system for investigating the adsorption kinetics and thermodynamic. The results showed no significant changes in either the material crystallinity or specific surface area, but the changes of surface functional groups identified the anchored ammine modifier. Kinetic modeling showed pseudo-second-order model best fitted the experimental data for both adsorbents. Moreover, the thermodynamic studies represented the chemisorption interaction of modified halloysite with the adsorbate since the average adsorption enthalpy values are at 44.3 kJ/mol and 41.70 kJ/mol for Cr(III) and Ni(II), respectively.