Open AccessCis-Dioxomolybdenum (VI) Complexes with N-donor Macrocyclic Ligands
Publication year - 2021
Publication title -
biointerface research in applied chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.216
H-Index - 11
ISSN - 2069-5837
DOI - 10.33263/briac121.13521364
Subject(s) - octahedron , molybdenum , schiff base , chemistry , chelation , metal , ligand (biochemistry) , monomer , octahedral molecular geometry , crystallography , polymer chemistry , medicinal chemistry , inorganic chemistry , stereochemistry , crystal structure , organic chemistry , receptor , biochemistry , polymer
The preparation of one monomeric [MoO2(L)](acac)2 having a Schiff base came by condensation of di-2-furanylethanedione with 2,3-diaminotoluene and 4 different complexes having formulation [MoO2(ML)](acac)2, from the result of [MoO2(L)](acac)2 with 1,3-diketones will be described with this paper. The preparation of each of these five MoO2 (VI) complexes was symbolized by thermal studies, UV-Vis, IR, elemental analyses, NMR, and molar conductance. The coordination number of molybdenum metal will be six. All 5 complexes of MoO2(VI) have a geometry of distorted octahedral arrangement. The octahedral arrangement of Mo-metal in prepared complexes is finished by 2 oxo O-atoms and 4 N-atoms from the synthesized ligand. All of the synthesized complexes demonstrated moderate action against S. aureus and S. typhi. The progression inside the antibacterial task being defined on the thought of chelation speculation.