Open AccessEnhanced Physical and Mechanical Properties of Flake–Shape/Vinyl-ester Nanocomposites Through Surface Modification of Graphene and Glass Flake: A Comparison with Simulated Data
Publication year - 2020
Publication title -
biointerface research in applied chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.216
H-Index - 11
ISSN - 2069-5837
DOI - 10.33263/briac114.1131611337
Subject(s) - dynamic mechanical analysis , materials science , composite material , surface modification , glass transition , vinyl ester , nanocomposite , flexural modulus , graphene , silane , flexural strength , ultimate tensile strength , absorption of water , dynamic modulus , polymer , chemical engineering , copolymer , nanotechnology , engineering
: The main goal of this work was to investigate the effects of silane-modified graphene nanosheets (MGNS) and modified nanoglass flakes (MNGF) on the physical and mechanical properties of vinyl-ester resin (VER) composites. The surface modification was evaluated about these composites' physical and mechanical behavior by techniques such as water absorption, tensile, three-point bending, and dynamic mechanical thermal analysis (DMTA). The analytical data revealed that the silane functionalized nanocomposites improved the interface between the nanosheets and vinyl-ester matrix. It was found that surface modification could significantly improve the dispersion and adhesion of GNS and nanoglass flakes (NGF) compared with those of neat vinyl-ester and unmodified composites. The presence functionalization of NGF and graphene nanosheets (GNS) in vinyl-ester formulation did affect the tensile and flexural strength and modulus, water absorption, and storage modulus. GNS/VER exhibited higher tensile and flexural strength and modulus than the original composite. DMTA results also showed incorporation of NGF and GNS decreased glass transition and increased storage modulus relative to neat composites. Nonetheless, the incorporation of functionalized graphene nanosheets and nano glass flakes represent higher Tg and storage modulus.