Phase equilibria for the carbon dioxide + cyclopentane + cyclohexane system at high pressures | Zendy

Mihaela Ioniţă | Zendy; Sergiu Sima | Zendy; Martín Cismondi | Zendy; Catinca Secuianu | Zendy

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Phase equilibria for the carbon dioxide + cyclopentane + cyclohexane system at high pressures

Author(s) -

Mihaela Ioniţă,

Sergiu Sima,

Martín Cismondi,

Catinca Secuianu

Publication year - 2021

Publication title -

revue roumaine de chimie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.135

H-Index - 21

ISSN - 0035-3930

DOI - 10.33224/rrch.2021.66.3.11

Subject(s) - cyclopentane , cyclohexane , ternary operation , isothermal process , thermodynamics , carbon dioxide , chemistry , van der waals force , volume (thermodynamics) , equation of state , analytical chemistry (journal) , chromatography , organic chemistry , physics , molecule , computer science , programming language

Isothermal vapor–liquid equilibrium measurements for the ternary mixture carbon dioxide + cyclopentane + cyclohexane at 353.15 K are reported. Phase equilibrium measurements were made in a high-pressure visual cell with variable volume using a static-analytical method with phases sampling by rapid online sample injectors (ROLSI) coupled to a gas chromatograph (GC) for analysis. The new measured data were modelled with the RK–PR equation of state (EoS) coupled with classical van der Waals (two-parameter conventional mixing rule, 2PCMR).

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