Open AccessReactions of heteroleptic [Cu(acac)(AA)(H2O)]+ complexes with carboxylate anions (acac- = acetylacetonate, AA = 2,2’-bipyridine, 1,10-phenanthroline)
Author(s) -
Paul A. TARABUTA,
Cătălin Maxim,
Marius Andruh
Publication year - 2021
Publication title -
revue roumaine de chimie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.135
H-Index - 21
ISSN - 0035-3930
DOI - 10.33224/rrch.2021.66.1.04
Subject(s) - isophthalic acid , chemistry , carboxylate , phenanthroline , ligand (biochemistry) , dimethylformamide , bipyridine , polymer chemistry , medicinal chemistry , zigzag , crystal structure , inorganic chemistry , stereochemistry , crystallography , organic chemistry , receptor , biochemistry , geometry , mathematics , solvent , polyester , terephthalic acid
The reactions of [Cu(acac)(AA)(H2O)]+ species (AA = 2,2’-bipyridine, 1,10-phenanthroline) with anions derived from 4-methylphenol-2,6-dicarboxylic (H3MeIPA) and isophthalic acids (H2IPA) generate new complexes, which result by substituting the acetylacetonato ligand by carboxylato ones: [Cu(bipy)(HMeIPA)(H2O)]∙0.5H2O∙DMF 1 (DMF = dimethylformamide), 1∞[Cu(bipy)(IPA)(H2O)2]∙H2O∙DMF 2, and 1∞[Cu(phen)(IPA)(H2O)]∙DMF 3. The crystal structures of 1 - 3 have been solved. Compound 1 is a mononuclear complex, while compounds 2 and 3 are one-dimensional coordination polymers with a zigzag topology.