Open AccessELECTROCHEMICAL SYNTHESIS OF IRON MONOSELENIDE THIN FILMS
Author(s) -
Aydan Zeynalova,
AUTHOR_ID,
S.P. Javadova,
V.A. Majidzade,
A.M. Aliyev,
AUTHOR_ID,
AUTHOR_ID,
AUTHOR_ID
Publication year - 2021
Publication title -
kimya problemləri
Language(s) - English
Resource type - Journals
eISSN - 2522-1655
pISSN - 2221-8688
DOI - 10.32737/2221-8688-2021-4-262-271
Subject(s) - electrolysis , electrochemistry , electrolyte , electrode , materials science , deposition (geology) , polarization (electrochemistry) , thin film , metal , analytical chemistry (journal) , metallurgy , inorganic chemistry , chemical engineering , chemistry , nanotechnology , paleontology , chromatography , sediment , engineering , biology
In the presented research work, the kinetics and mechanism of the deposition process of thin iron, selenium and Fe-Se films have been studied by recording a cyclic and linear polarization curves by potentiodynamic method using Pt and Ni electrodes. Individual and co-deposition potential areas of the components of the electrolyte on the Pt electrode were determined. In order to determine the optimal electrolysis mode and electrolyte composition, the effect of various factors (concentration of initial components, temperature, etc.) on the co-electrodeposition process of Fe-Se was studied. In addition, Fe-Se samples deposited on the surface of Ni electrodes were thermally treated at 4500C and studied by SEM and X-ray phase analysis methods. Elemental analysis of the films shows that they contain 42.2% Fe and 57.8% Se.