Open AccessSYNTHESIS OF 1-(P-VINYLPHENYL)-2- DIETHYLAMINOMETHYLCYCLOPROPANE AND ITS RADICAL COPOLYMERIZATION WITH METHYL METHACRYLATE
Author(s) -
A. I. Sadygova
Publication year - 2021
Publication title -
kimya problemləri
Language(s) - English
Resource type - Journals
eISSN - 2522-1655
pISSN - 2221-8688
DOI - 10.32737/2221-8688-2021-3-173-178
Subject(s) - copolymer , methyl methacrylate , monomer , polymer chemistry , chemistry , methacrylate , organic chemistry , polymer
The radical copolymerization of 1-(p-vinylphenyl)-2-diethylaminomethylcyclopropane with methyl methacrylate was carried out and some regularities of the process examined. Values of constants of relative activity of monomers were determined and Q-e parameters calculated on Alfrey and Price. Copolymerization constants of this compound (r1) with methyl methacrylate (r2), calculated on the FinemanRoss method, are as follows: r1 = 0.95, r2 = 0.33, Q and e parameter values: Q1 = 1.80, e1 = -0.72, respectively. The photochemical structuring of the copolymer was studied. It was established that the obtained copolymer has a sufficiently high biomedical activity which opens up the possibility of its using as bactericides and fungicides