Open AccessPOLYMERIZATION OF 8-ACETOXYTETRACYCLO[4.4.12,5.17,10.01,6]DODEC-3-ENE AND ITS COPOLYMERIZATION WITH ACRYLIC ACIDS
Author(s) -
E.K. Makhmudova,
R. A. Rasulova,
V. S. Kadyrly,
M.J. Ibrahimova,
J.H. Ismailova
Publication year - 2021
Publication title -
azərbaycan kimya jurnalı/azerbajčan himiâ žurnaly
Language(s) - English
Resource type - Journals
eISSN - 2522-1841
pISSN - 0005-2531
DOI - 10.32737/0005-2531-2021-3-31-37
Subject(s) - copolymer , polymerization , monomer , polymer chemistry , solvent , ene reaction , polymer , catalysis , benzene , materials science , chemistry , organic chemistry
The reaction of radical polymerization of 8-acetoxytetracyclo[4.4.12,5.17,10.01,6]dodec-3-ene as well as its copolymerization with methacrylic acids in the presence of BF3·OEt2 in bulk and in the medium of organic solvent, particularly in benzene was investigated. The influence of various factors: the amount of catalyst, temperature and reaction time on the process of polymerization, as well as the influence of the monomer ratio on the copolymerization process was studied. The structure of the obtained homo- and copolymers was confirmed by IR spectroscopy and the thermal stability of the obtained polymers and their cured products was studied