Open AccessMECHANISM OF BIOMIMETIC OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE BY HYDROGEN PEROXIDE
Author(s) -
S.A. Aghamammadova
Publication year - 2021
Publication title -
azərbaycan kimya jurnalı/azerbajčan himiâ žurnaly
Language(s) - English
Resource type - Journals
eISSN - 2522-1841
pISSN - 0005-2531
DOI - 10.32737/0005-2531-2021-1-61-66
Subject(s) - cyclohexanone , cyclohexane , cyclohexanol , hydrogen peroxide , chemistry , selectivity , catalysis , photochemistry , organic chemistry
The process of gas-phase oxidation of cyclohexane was studied in the presence of a heterogeneous biomimetic catalyst (per-FTPhPFe(III)OH/Al2O3), at 130–2500C, in which high yields of cyclohexanone and cyclohexanol were obtained up to 25.2% with a selectivity of ~80% at a cyclohexane conversion of 34%. The mechanism of the conversion of cyclohexane to cyclohexanone has been studied in detail, and the coherently synchronized character of the reaction proceeding is shown