
Aminolysis of poly(ethylene terephthalate) waste bottle with tetra/hexamethylene diamine and characterization of alpha, ohmega-diamine products
Author(s) -
Cuong Ngoc Hoang,
Yen Hoang Dang
Publication year - 2017
Publication title -
khoa học và công nghệ: tự nhiên
Language(s) - English
Resource type - Journals
ISSN - 2588-106X
DOI - 10.32508/stdjns.v1it2.446
Subject(s) - aminolysis , diamine , polymer chemistry , hexamethylenediamine , ethylene diamine , bottle , chemistry , organic chemistry , materials science , nuclear chemistry , catalysis , polyamide , composite material
The aminolysis of poly(ethylene terephthalate) (PET) waste bottle with excess amount of aliphatic diamines, such as tetramethylenediamine (TMDA) and hexamethylenediamine (HMDA) without catalyst has been carried out. Each trimers and pentamers in the obtained products were isolated and characterized by FTIR, NMR, HPLC methods. Although an excess of diamine was employed, longer blocks of oligomers were still formed as minor products.