Open AccessSynthesis, characterisation and reactions of cationic complexes of Arylantimony (III) chlorides ArnSbCl3-n with perchlorate and tetrafluoroborate anions
Author(s) -
Ram Kumar Yadav
Publication year - 2013
Publication title -
international journal of applied sciences and biotechnology
Language(s) - English
Resource type - Journals
ISSN - 2091-2609
DOI - 10.3126/ijasbt.v1i2.8204
Subject(s) - cationic polymerization , tetrafluoroborate , perchlorate , chemistry , thiourea , pyridine , trifluoromethanesulfonate , medicinal chemistry , polymer chemistry , inorganic chemistry , ion , organic chemistry , catalysis , ionic liquid
Several hitherto unreported cationic complexes of the general formula [Ar2SbL][Y] and [ArSbL2][Y]2 [ Where, Ar = C6H5, L = -Picoline, Pyridine, Ph3AsO, hexamethyl phosphoramide (HMPA), thiourea (TU) and Y = ClO4- BF4-] have been synthesized and characterized by solid state IR, 1H NMR, elemental analysis, conductance and molecular weight measurements. The physico- chemical data, cations [Ar2SbL]+1 and[ArSbL2]+2 are assigned a pyramidal structure