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Treatment of petroleum refinery wastewater by electrochemical oxidation using graphite anodes
Author(s) -
Sajjad Sarhan Jawad,
Ali H. Abbar
Publication year - 2019
Publication title -
mağallaẗ al-qādisiyyaẗ li-l-ʻulūm al-handasiyyaẗ
Language(s) - English
Resource type - Journals
eISSN - 2411-7773
pISSN - 1998-4456
DOI - 10.30772/qjes.v12i3.609
Subject(s) - effluent , refinery , oil refinery , electrochemistry , phenol , wastewater , anode , graphite , pulp and paper industry , chemistry , environmental science , nuclear chemistry , waste management , electrode , environmental engineering , organic chemistry , engineering
An electrochemical oxidation method was performed in a batch electrochemical reactor using graphite anodes for treating an effluent obtained from Al-Diwaniyah petroleum refinery plant. The effective f process parameters like current density (4-20m Acm-2), pH (3-9), and NaCl concentration (0-3 g/l) on the COD and phenol removal efficiency have been investigated. The results reveal that the best conditions were current density 12 mA cm-2, pH 7, NaCl concentration 2 gl-1 at a treatment time of 60 minutes. Under  best conditions of COD removal efficiency 100% and phenol removal efficiency 99.12% were obtained at current efficiency 33.5% and power consumption 59.9 kWh/kg COD. The anodic oxidation was proven to be efficient for treatment Al-Diwaniyah petroleum refinery effluent to get effluent with features in agreement with the standard limits for discharge to the environment at a lower cost.

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