Open AccessMulti-Element Determination of Trace Elements in B7-diesel Oil by High-Resolution Continuum Source Flame Atomic Absorption Spectrometry
Author(s) -
Heldiane Souza dos Santos,
Alexandre de Jesus,
Diane O. Laroque,
Clarisse Maria Sartori Piatnicki,
Márcia M. da Silva
Publication year - 2021
Publication title -
brjac brazilian journal of analytical chemistry
Language(s) - English
Resource type - Journals
eISSN - 2179-3433
pISSN - 2179-3425
DOI - 10.30744/brjac.2179-3425.ar-53-2020
Subject(s) - diesel fuel , analytical chemistry (journal) , certified reference materials , atomic absorption spectroscopy , nitric acid , chemistry , graphite furnace atomic absorption , detection limit , trace element , aqueous solution , chromatography , inorganic chemistry , physics , organic chemistry , quantum mechanics
In this work, a method for sequential multi-element determination of Cu, Fe, Ni, Pb, Zn, Al, Cr and Sn in B7-diesel oil samples by high-resolution continuum source flame atomic absorption spectrometry (HR-CS F AAS) was proposed. The sample preparation was based on formation of microemulsion (ME), which was investigated through a three-phase diagram. The ME composition adopted was B7-diesel oil (3.3 g), aqueous phase containing nitric acid (1.4 mol L-1, 300 μL) and n-propanol (up to 10 mL). The use of surfactant Triton X-100 in the formation of ME was also evaluated. Limits of detection in the range of 0.01 – 0.4 mg kg-1 were obtained. Spike-recovery tests were accomplished and the results varied between 93 and 124%. The accuracy of the proposed method was confirmed by the analysis of certified reference material (CRM) NIST SRM 1084a (Wear-Metals in Lubricating Oil); there was no statistical difference between the obtained results and the certified values (at 95% confidence level). Twelve B7-diesel oil samples were analyzed and Cu, Fe and Cr were found in three samples. The proposed method was simple, fast and accurate. The sequential multi-element determination of trace elements presented advantages as low costs and reduction in analysis time, being appropriate for routine analysis.