Open AccessMicrostructure properties of lead silicate glasses
Author(s) -
Dunia K. M. Al-Nasrawy
Publication year - 2019
Publication title -
iraqi journal of physics
Language(s) - English
Resource type - Journals
eISSN - 2664-5548
pISSN - 2070-4003
DOI - 10.30723/ijp.v13i28.246
Subject(s) - materials science , lead oxide , microstructure , oxide , silicate , fourier transform infrared spectroscopy , infrared spectroscopy , octahedron , mineralogy , crystal structure , chemical engineering , crystallography , metallurgy , chemistry , organic chemistry , engineering
In the present work, lead silicate glasses have been prepared withdifferent amount of lead oxide content. Structure properties such asX-ray diffraction, AFM, and FTIR analyses have been done. Theexceeding of PbO content more than 25wt% revealed a decreasing indensity. The X- ray revealed that the strongest peak related toHexagonal silica dioxide and the other crystal phases formed wererelated to silica oxide (SiO2) and lead oxide (PbO). Growth anddecayed phases in X-ray have been observed with changing leadoxide content. Homogeneous surface was obtained using AFManalyzer with an average diameter around 100 nm. Infrared spectrumis characterized by the presence of large absorption band between1200 and 900cm-1 and have its maximum at 1080 cm-1 which istypical to stretching vibrations of Si–O–Si bonds, another bandsnoticed were attributed to Pb–O–Pb, Pb–O–Si, [AlO4]-tetrahedron,and to Si–O–Al bond.