Open AccessState of ions and water molecules in the water salt solutions of polyacrylamide and co-polymer of “acrylamide–acrylic acid Na/k salt”
Author(s) -
В. С. Солдатов,
Д. Н. Давлюд,
Т. В. Безъязычная,
Е. В. Воробьева,
Е. Г. Косандрович,
П. Д. Воробьев
Publication year - 2020
Publication title -
doklady nacionalʹnoj akademii nauk belarusi
Language(s) - English
Resource type - Journals
eISSN - 2524-2431
pISSN - 1561-8323
DOI - 10.29235/1561-8323-2019-63-6-695-703
Subject(s) - aqueous solution , chemistry , polymer , molecule , covalent bond , carboxylate , polyacrylamide , monomer , intermolecular force , salt (chemistry) , acrylic acid , inorganic chemistry , polyelectrolyte , acrylamide , polymer chemistry , organic chemistry
Geometrical and electronic parameters of the microstates of the molecular models of polyacrylamide and co-polymers of acrylamide-acrylic acid in aqueous solutions of sodium and potassium chlorides were computed by the non-empirical SCF MO LCAO method with the use of the basis MINI Huzinaga. The models contained four monomeric units of the polymer, including two metal carboxylate groups, 80 water molecules and two pairs of ions Na+ and Cl– or K+ and Cl–. It follows from the calculation results that there is a principal difference in the hydration of Na+ and K+: the Na+‧‧‧О2– bond is shorter than the sum of the radii of the interacting ions, while the k+‧‧‧O2– bond is equal or longer. This indicates that in the first case, the bonds are partially covalent, while in the second one they are pure electrostatic. All elements of the molecular models in the both cases are combined by the intermolecular bonds forming a spatial net. The polymer molecules have a flexible chain with oxygen containing functional groups that are built into the structure of the salt solutions without distorting it. We assume that this is the main reason for the good solubility of the studied polymers in the aqueous salt solutions.