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PENGEMBANGAN KATALIS BERBASIS NiMo ALUMINA UNTUK REAKSI HIDRODEOKSIGENASI MINYAK NABATI MENJADI BIOAVTUR
Author(s) -
Bralin Dwiratna,
Soebagjo Soebagjo
Publication year - 2015
Publication title -
jurnal energi dan lingkungan (enerlink)
Language(s) - English
Resource type - Journals
ISSN - 0216-9541
DOI - 10.29122/elk.v11i2.1580
Subject(s) - hydrodeoxygenation , selectivity , catalysis , bar (unit) , nuclear chemistry , materials science , boron , chemistry , organic chemistry , physics , meteorology
Catalysts NiMoP/γ-Al O -B O have been successfully synthesized by impregnation method. The 2 3 2 3catalyst was developed to process of vegetable oil hydrodeoxygenation (HDO). The effect of theaddition of boron and phosphorus on the activity and selectivity was studied in this research . Inaddition , the determination of appropriate operating conditions were also studied in order to obtainproducts with good conversion and selectivity. The research was conducted on the preparation of thehydrodeoxygenation catalyst , test the activity and selectivity of hydrodeoxygenation catalysts, andcatalysts characterization using BET , XRD and AAS . To determine the performance of the catalyst ,the hydrodeoxygenation catalysts were tested their activity and selectivity which took place in a batchreactor at a pressure of 20-60 bar and a temperature of 320-360 ° C. The composition of products wereanalyzed by using a Gas Cromatography . From the implementation of HDO reaction of vegetable oilwith NiMoP( 0.6 % )/γ- Al O - B O (1.7 %) catalyst, the value of conversion obtained was 81.45 % at 60 2 3 2 3o bar operating pressure conditions and temperature 360 C .Keywords: vegetable oil , hidrodeoksigenasi , catalyst Nimo - γalumina

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