Open AccessInorganic Electrosynthesis: a Green Chemical Method for tin Complexes
Author(s) -
Víctor M. Jiménez Pérez,
Blanca Flores,
Boris I. Kharisov,
Eugenio Hernández Fernández,
Susana López Cortina,
Noemí Aksman,
Rosalba Ramírez Durón
Publication year - 2011
Publication title -
química hoy chemistry sciences
Language(s) - English
Resource type - Journals
ISSN - 2007-1183
DOI - 10.29105/qh1.3-224
Subject(s) - electrosynthesis , tin , amine gas treating , chemistry , electrochemistry , intermolecular force , anode , inorganic chemistry , methanol , carbon 13 nmr , solvent , mass spectrometry , polymer chemistry , organic chemistry , molecule , electrode , chromatography
SnIV complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 1H and 13C-NMR, IR, and high resolution mass spectrometry. However, all were not enough soluble in organic solvent in order to record its 119Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.