Open AccessINTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY
Author(s) -
Dame Seye,
Assane Touré,
Cheikh Diop,
Libasse Diop
Publication year - 2020
Publication title -
journal of engineering studies and research
Language(s) - English
Resource type - Journals
eISSN - 2344-4932
pISSN - 2068-7559
DOI - 10.29081/jesr.v26i3.208
Subject(s) - bromide , intermolecular force , octahedron , ammonium bromide , chemistry , hydrogen bond , supramolecular chemistry , metal , infrared , inorganic chemistry , methanol , crystallography , crystal structure , molecule , organic chemistry , pulmonary surfactant , biochemistry , physics , optics
On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.