Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control | Zendy

Axel G. Griesbeck | Zendy; Seyma Bozkus | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control

Author(s) -

Axel G. Griesbeck,

Seyma Bozkus

Publication year - 2021

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2021.868

Subject(s) - intersystem crossing , selectivity , spin (aerodynamics) , multiplicity (mathematics) , chemistry , photochemistry , hyperfine structure , molecule , spin–orbit interaction , chemical physics , coupling (piping) , reactivity (psychology) , computational chemistry , materials science , atomic physics , excited state , physics , organic chemistry , condensed matter physics , catalysis , mathematical analysis , mathematics , singlet state , metallurgy , thermodynamics , medicine , alternative medicine , pathology

Spin chemistry involving small organic molecules without heavy atoms is highly sensitive to spin-orbit-coupling (SOC) modulating biradical conformation as well as hyperfine coupling (HFC) modulating magnetic isotope interactions. Several easily available reaction properties such as chemo-, regio-, and diastereoselectivity as well as quantum yields serve as analytical tools to follow intersystem crossing dynamics and allows titrating spin selectivities.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research