Copper, Boron and Vinyl Epoxides: from 1,4-Diols to Cyclopropylboronates | Zendy

Luis Nóvoa | Zendy; Laura Trulli | Zendy; Alejandro Parra | Zendy; Mariola Tortosa | Zendy

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Copper, Boron and Vinyl Epoxides: from 1,4-Diols to Cyclopropylboronates

Author(s) -

Luis Nóvoa,

Laura Trulli,

Alejandro Parra,

Mariola Tortosa

Publication year - 2020

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2020.852

Subject(s) - epoxide , alkene , allylic rearrangement , boron , chemistry , copper , reactivity (psychology) , organic chemistry , diol , polymer chemistry , catalysis , medicine , alternative medicine , pathology

Herein we describe the reactivity found between vinyl epoxides and catalytically generated copper-boryl complexes. By tuning the substituents of the alkene and/or the reaction conditions, 1,4-diols, allylic alcohols or cyclopropylboronates can be prepared. The stereochemical information of the vinyl epoxide is transferred to the products with high levels of stereocontrol.

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