Open AccessRadical Reactions of Boron-Ate Complexes Promoting a 1,2-Metallate Rearrangement
Author(s) -
Nicholas D. C. Tappin,
Philippe Renaud
Publication year - 2020
Publication title -
chimia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2020.33
Subject(s) - radical , boron , chemistry , rearrangement reaction , medicinal chemistry , photochemistry , organic chemistry , catalysis
Recently there has been an explosion of interest in the synthetic community for the addition of radicals into unsaturated organoboron-ate complexes. This review will give a concise outline for radical processes involving boron-ate complexes which trigger a subsequent anionotropic rearrangement.