Open Accesstert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon–Nitrogen Bond Forming Reactions
Author(s) -
Johana Ramirez Hernandez,
Fabrice Chemla,
Franck Ferreira,
Olivier Jackowski,
Julie Oble,
Alejandro PérezLuna,
Giovanni Poli
Publication year - 2016
Publication title -
chimia
Language(s) - English
Resource type - Journals
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2016.84
Subject(s) - nucleophile , nitrogen , amination , chemistry , reagent , amine gas treating , carbon fibers , organic chemistry , catalysis , materials science , composite number , composite material
The use of tert-butanesulfinamides as nitrogen nucleophiles in carbon-nitrogen bond forming reactions is reviewed. This field has grown in the shadow of the general interest in N-tert-butanesulfinyl imines for asymmetric synthesis and occupies now an important place in its own right in the chemistry of the chiral amine reagent tert-butanesulfinamide. This article provides an overview of the area and emphasizes recent contributions wherein the tert-butanesulfinamides act as chiral auxiliaries or perform as nitrogen donors in metal-catalyzed amination reactions.