Open AccessSynthesis and Reactivity of Zn–Biphenyl Metal–Organic Frameworks, Introducing a Diphenylphosphino Functional Group
Author(s) -
Marco Ranocchiari,
Jeroen A. van Bokhoven
Publication year - 2013
Publication title -
chimia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2013.397
Subject(s) - biphenyl , reactivity (psychology) , flexibility (engineering) , group (periodic table) , metal organic framework , surface modification , organic synthesis , materials science , combinatorial chemistry , metal , chemistry , topology (electrical circuits) , organic chemistry , catalysis , mathematics , medicine , statistics , alternative medicine , pathology , adsorption , combinatorics
Structural features, synthesis, and reactivity of Zn–biphenyl metal–organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn–biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.