R-isophthalic Acid-based Coordination Polymers (R = Hydrogen or Bromine) | Zendy

Renyun Zhang | Zendy; Qihan Gong | Zendy; Thomas J. Emge | Zendy; Debasis Banerjee | Zendy; Jing Li | Zendy

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R-isophthalic Acid-based Coordination Polymers (R = Hydrogen or Bromine)

Author(s) -

Renyun Zhang,

Qihan Gong,

Thomas J. Emge,

Debasis Banerjee,

Jing Li

Publication year - 2013

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2013.393

Subject(s) - isophthalic acid , bromine , pyridine , polymer , coordination polymer , ligand (biochemistry) , metal organic framework , chemistry , crystallography , materials science , stereochemistry , medicinal chemistry , organic chemistry , polyester , terephthalic acid , biochemistry , receptor , adsorption

Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

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