?-Trimethylsilylmethylamine Radical Cation in the Synthesis of Cyclic Amines and Beyond | Zendy

Ganesh Pandey | Zendy; Debasis Dey | Zendy; Smita R. Gadre | Zendy

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?-Trimethylsilylmethylamine Radical Cation in the Synthesis of Cyclic Amines and Beyond

Author(s) -

Ganesh Pandey,

Debasis Dey,

Smita R. Gadre

Publication year - 2013

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2013.30

Subject(s) - cyclic amines , chemistry , olefin fiber , radical ion , amine gas treating , electron transfer , combinatorial chemistry , photoinduced electron transfer , organic chemistry , ion , catalysis

The evolution of chemistry associated with the photoinduced electron transfer (PET)-generated ?-trimethylsilylmethylamine radical cation cyclization to a tethered olefin to synthesize cyclic amine structural frame works is presented in chronological order. The importance of this interesting chemistry is demonstrated by the synthesis of several novel glycosidase inhibitors.

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