Open Access?-Trimethylsilylmethylamine Radical Cation in the Synthesis of Cyclic Amines and Beyond
Author(s) -
Ganesh Pandey,
Debayan Dey,
Gadre
Publication year - 2013
Publication title -
chimia
Language(s) - English
Resource type - Journals
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2013.30
Subject(s) - cyclic amines , chemistry , olefin fiber , radical ion , amine gas treating , electron transfer , combinatorial chemistry , photoinduced electron transfer , organic chemistry , ion , catalysis
The evolution of chemistry associated with the photoinduced electron transfer (PET)-generated ?-trimethylsilylmethylamine radical cation cyclization to a tethered olefin to synthesize cyclic amine structural frame works is presented in chronological order. The importance of this interesting chemistry is demonstrated by the synthesis of several novel glycosidase inhibitors.