Teaching Enantioselectivity to C–H Bond Functionalizations: Initial Steps of a Rather Long Shot | Zendy

Nicolai Cramer | Zendy

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Teaching Enantioselectivity to C–H Bond Functionalizations: Initial Steps of a Rather Long Shot

Author(s) -

Nicolai Cramer

Publication year - 2012

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2012.869

Subject(s) - enantioselective synthesis , rhodium , surface modification , catalysis , palladium , chemistry , metal , combinatorial chemistry , one shot , organic chemistry , stereochemistry , engineering , mechanical engineering

The direct functionalization of non-activated C–H bonds, especially in an enantioselective manner, requires metal catalysts equipped with ligands with specifically designed properties. Examples for asymmetric C(sp2)–H and C(sp3)–H functionalizations using palladium- and rhodium catalysts are shown. This work was rewarded by the 2012 Werner Prize of the Swiss Chemical Society.

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