Open AccessThe Art of Catching and Probing Single Molecules
Author(s) -
Henricus J.W. Zandvliet
Publication year - 2012
Publication title -
chimia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2012.52
Subject(s) - scanning tunneling microscope , molecule , phthalocyanine , conductance , substrate (aquarium) , semiconductor , materials science , quantum tunnelling , scanning tunneling spectroscopy , nanowire , electrode , atom (system on chip) , nanotechnology , spectroscopy , chemical physics , chemistry , optoelectronics , condensed matter physics , physics , oceanography , organic chemistry , quantum mechanics , geology , computer science , embedded system
Probing the electronic properties of an individual molecule is a far from trivial task. In order to measure, for instance, the conductance of a single molecule, the molecule must be contacted by two nanoscopic electrodes. Here we will give two examples of how a single molecule can be caught between two metallic electrodes. In the first example the conductance of a single octanethiol molecule is measured by trapping the molecule between an atomic Pt chain on a semiconductor surface and the apex of a scanning tunneling microscope tip. In the second example a Cu-phthalocyanine molecule is caught between two adjacent nanowires on a semiconductor surface. In this 'bridge' adsorption configuration the core of the CuPc molecule, i.e. the Cu atom, is fully decoupled from the underlying substrate. The electronic properties of the core of Cu-phthalocyanine molecule are probed with scanning tunneling spectroscopy.