Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry | Zendy

Ibrahima Cissokho | Zendy; AnneMarie Farnet | Zendy; Élisée Ferré | Zendy; Michèle P. Bertrand | Zendy; Gérard Gil | Zendy; Stéphane Gastaldi | Zendy

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Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

Author(s) -

Ibrahima Cissokho,

AnneMarie Farnet,

Élisée Ferré,

Michèle P. Bertrand,

Gérard Gil,

Stéphane Gastaldi

Publication year - 2012

Publication title -

chimia international journal for chemistry

Language(s) - Uncategorized

Resource type - Journals

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.2012.435

Subject(s) - chemistry , radical , radical cyclization , electron transfer , photochemistry , enzyme , hydroxyl radical , free radical reaction , combinatorial chemistry , organic chemistry

The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified with a radical cascade.

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