Open AccessEnzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry
Author(s) -
Ibrahima Cissokho,
AnneMarie Farnet,
E. Ferré,
M. Bertrand,
G. Gil,
Stéphane Gastaldi
Publication year - 2012
Publication title -
chimia
Language(s) - Uncategorized
Resource type - Journals
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2012.435
Subject(s) - chemistry , radical , photochemistry , radical cyclization , electron transfer , hydroxyl radical , free radical reaction , radical ion , combinatorial chemistry , organic chemistry , ion
The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified with a radical cascade.