Open AccessStereoselective Radical Translocations
Author(s) -
Philippe Renaud,
Florent Beaufils,
Fabrice Dénès,
Laurence Feray,
Christoph Imboden,
N. Yu. Kuznetsov
Publication year - 2008
Publication title -
chimia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2008.510
Subject(s) - chromosomal translocation , intramolecular force , stereoselectivity , chemistry , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , biochemistry , gene
The stereochemical outcome of intramolecular radical mediated hydrogen transfer (= radical translocation) is discussed. Low to excellent levels of stereocontrol are observed making such processes attractive for applications in target-oriented synthesis.