Desymmetrisation of Dienylsilanes. Stereoselective Access to Cyclitols and Carba-Sugars | Zendy

Yannick Landais | Zendy

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Desymmetrisation of Dienylsilanes. Stereoselective Access to Cyclitols and Carba-Sugars

Author(s) -

Yannick Landais

Publication year - 1998

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1998.104

Subject(s) - dihydroxylation , enantioselective synthesis , stereoselectivity , scope (computer science) , chemistry , stereochemistry , organic chemistry , computer science , catalysis , programming language

The diastereo- and enantioselective functionalisation of 1,4-cyclohexadienylsilanes using Sharpless asymmetric dihydroxylation and aminohydroxylation offers a straightforward access to various classes of potent inhibitors of glycosidases. The scope and limitation of this desymmetrisation method is illustrated here with the synthesis of various conduritols, carba-sugars and carba-C-disaccharides.

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