Catalytic Enantioselective Reactions from Research to Application. Diarylmethanol-Containing Auxiliaries as a Study Case | Zendy

Dieter Seebàch | Zendy; Albert K. Beck | Zendy

Open Access

Catalytic Enantioselective Reactions from Research to Application. Diarylmethanol-Containing Auxiliaries as a Study Case

Author(s) -

Dieter Seebàch,

Albert K. Beck

Publication year - 1997

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1997.293

Subject(s) - enantioselective synthesis , moiety , catalysis , stoichiometry , aryl , chemistry , organic chemistry , metal , combinatorial chemistry , alkyl

Chiral auxiliaries – in the broadest possible definition of the term – can be obtained by Grignard reactions of Aryl-MgX with chiral esters R*CO2R. The products formed all contain a diarylmethanol structural moiety. They can be used in stoichiometric and catalytic enantioselective reactions, preferably as ligands on metal centers. They have also found applications for enantioselective inclusions, for solid-phase reactions, and for liquid-crystal preparations.

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