Open AccessSelective Photocyclization of Amino Acids in Dipeptides
Author(s) -
Stephan Sauer,
Christian Staehelin,
Caroline Wyss,
Bernd Giese
Publication year - 1997
Publication title -
chimia international journal for chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.1997.23
Subject(s) - amino acid , valine , chemistry , stereochemistry , combinatorial chemistry , biochemistry
Amino acids in dipeptides which are substituted at the N-atom by a benzoylalkyl group can be selectively photocyclized via a triplet biradical. With valine as amino acid the cyclization leads mainly to one product out of eight possible isomers.
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