Organic Synthesis with α-Silylcarbonyl Compounds | Zendy

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Organic Synthesis with α-Silylcarbonyl Compounds

Author(s) -

Yannick Landais

Publication year - 1996

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1996.641

Subject(s) - synthon , organosilicon , silylation , organic synthesis , chemistry , organic chemistry , simple (philosophy) , combinatorial chemistry , nanotechnology , catalysis , materials science , philosophy , epistemology

Our interest in organosilicon compounds has led us to examine the chemistry of rarely used α-silylcarbonyl compounds. Possible applications of these synthons are not covered totally here, but a few examples along these lines should demonstrate the utility of these structurally simple substrates in organic synthesis. The preparation of the α-silyl esters and some examples of their stereocontrolled conversion into polysubstituted tetrahydrofurans is presented.

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