Ligand Effects on the Rate and Mechanism of Solvent Exchange at Rhodium(III) and Iridium(III) | Zendy

Antonio Cusanelli | Zendy; Lynda Nicula-Dadci | Zendy; Urban Frey | Zendy; André E. Merbach | Zendy

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Ligand Effects on the Rate and Mechanism of Solvent Exchange at Rhodium(III) and Iridium(III)

Author(s) -

Antonio Cusanelli,

Lynda Nicula-Dadci,

Urban Frey,

André E. Merbach

Publication year - 1996

Publication title -

chimia international journal for chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.387

H-Index - 55

eISSN - 2673-2424

pISSN - 0009-4293

DOI - 10.2533/chimia.1996.618

Subject(s) - iridium , rhodium , solvent , chemistry , reaction rate constant , ligand (biochemistry) , inorganic chemistry , catalysis , kinetics , organic chemistry , physics , biochemistry , receptor , quantum mechanics

The rate constants and activation parameters for solvent exchange for a series of RhIII and IrIII complexes of the form [M(H2O)6]3+ (M = Rh or Ir) and [Cp*M(S)3]2+ (M = Rh or Ir, and S = H2O, MeCN, or Me2SO) have been determined by NMR spectroscopy as a function of free-solvent concentration, temperature, and pressure, and the mechanisms for the respective exchange processes have been inferred.

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