Open AccessHigh-Pressure Stopped-Flow Study of Inclusion Reactions with α-Cyclodextrin: Dynamic Aspects in Host-Guest Interactions
Author(s) -
Pascal Bug,
Peter G. Lye,
Amira Abou Hamdan,
André E. Merbach
Publication year - 1996
Publication title -
chimia
Language(s) - English
Resource type - Journals
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.1996.615
Subject(s) - cyclodextrin , chemistry , inclusion compound , molecule , inclusion (mineral) , stopped flow , high pressure , kinetics , thermodynamics , organic chemistry , reaction rate constant , mineralogy , physics , classical mechanics
The full volume and entropy profiles of the inclusion reaction between α-cyclodextrin and the guest molecules, ethylorange (1) and mordant yellow 7 (2), have been constructed from variable-pressure and -temperature stopped-flow kinetic experiments.