Heteroatom-Substituted Radicals: 1,2-Asymmetric Induction
Author(s) -
Philippe Renaud
Publication year - 1996
Publication title -
chimia international journal for chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.1996.135
Subject(s) - heteroatom , radical , stereoselectivity , chemistry , lewis acids and bases , asymmetric induction , organic synthesis , combinatorial chemistry , organic chemistry , enantioselective synthesis , catalysis , ring (chemistry)
Radical reactions became during the last decade a very useful tool in organic synthesis. Spectacular progress has been made in the control of the stereoselectivity of these reactions. This contribution presents our recent results with 1- and 2-heteroatom substituted radicals in cyclic and acyclic systems. Several examples dealing with the use of Lewis acids to achieve high stereochemical control are presented.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom